Posts Tagged :

biodiesel

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Keep and make your diesel fuel cleaner 1024 768 Star Oilco

Keep and make your diesel fuel cleaner

Clean, dry, premium diesel

What is Clean Diesel? 

Clean diesel is free of the contaminants that harm modern diesel engines. Today, there is a gap between ASTM diesel standards and the ISO cleanliness standards needed for use in high pressure common rail engines. Anyone operating a modern clean diesel engine is seeing the effect, including injector replacement, DPF regeneration, and a host of other fuel quality related maintenance concerns we never saw twenty years ago. On top of all of that, today’s refined diesel fuels are less storage stable then ever before. What is on the bottom of your bulk tank can also complicate matters further. When diesel is bought wholesale it typically meets and exceeds ASTM required industry standards, but almost always requires additional filtration to avoid excessive engine wear and premature part failures.

Having clean diesel requires an additional amount of care. Namely, you need to make sure that the fuel is aggressively filtered at 4 microns to catch the microscopic particles that are big enough to damage your modern diesel engine’s high pressure fuel rail system. Furthermore, clean diesel is fuel that is free of water and stabilized with Premium Diesel to guarantee no bacteria, yeast and other creatures can grow and further contaminate the saddle tanks on your trucks.

For more on clean diesel, see Donaldson’s description of “The New Clean” for an in-depth explanation of what ISO cleanliness and filtration mean for your diesel fleet.

Making Diesel Cleaner!

Knowing the quality of your fuel is the first step. This is done by taking samples off of the bottom of your bulk storage, as well as a representative sample from your fuel dispenser. Lab tests of those samples will tell you if you have water, biological growth, or dirt issues with your storage. The contaminants in the tank being sampled are almost always visible, which is to say that they look horribly ugly. If your fuel quality assurance has been on autopilot, do not be surprised if you find this. After gathering knowledge about your fuel, the next step is to get your fuel quality clean.

Filtration and tank bottom sampling is the start. Beyond that, the only way to improve your fuel quality performance is to filter your fuel, ensure water is not getting into the tank through condensation, and additize it with a Premium Diesel additive to upgrade the performance of the fuel. Many fleets today are seeing injector wear and continual problems with particulate trap maintenance. This is a combination of water in fuel and microscopic particles not captured by a 10 or 30 micron filter used at most diesel dispensers. You have to filter more aggressively than this.

Clean, Dry, and Premium Diesel!  Where To Start?

The first step is sampling your bulk diesel tank. We check your bulk tank for water and dirt, and make sure to meet the specifications your engine is built for. Star Oilco can help by providing a complementary diesel test for those fleets interested in taking control of their fuel quality assurance. Usually when testing fuel, we take a sample off of the tank bottom as well as a representative sample out of the fuel dispensing nozzle.

What we usually find is ASTM specification diesel fuel (it meets ASTM spec) that is higher than you’d want (still in spec) for water with far more dirt than the OEM’s would want to see in your engine. This dirt fails to be within the “ISO Cleanliness” specifications recommended by engine manufacturers. Usually we also see water on the bottom of the fuel tank, which is a likely source for future or current biological growth in your fuel tank.

Star Oilco can help you fix this! The first step is to sample your fuel tank.

NOTE: If you have a current biological growth problem in your bulk fuel tank or fleet, your first step is to treat that effected fuel with a diesel microbiocide to kill the bugs growing in your tank. For more on this, see our Valvtect Plus 6 Diesel Microbiocide page.

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BioDiesel Feedstocks: Coconut Oil and Coffee Oil 1024 683 Star Oilco

BioDiesel Feedstocks: Coconut Oil and Coffee Oil

We are continuing our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. This week’s two feedstocks are Coconut Oil and Coffee Oil. Here is a link to the main page of feedstocks we have examined so far.

Coconut Oil

For this feedstock REG purchased refined, bleached, deodorized (RBD) coconut oil.The parts of a coconut tree.

As a background, lets talk a little bit about Coconut trees (Cocos nucifera) they are part of the palm tree family (Arecaceae) and they love sandy soils and can tolerate a high level of salt. The trees prefer regular rainfall, high humidity 70-80% and lots of sunshine.  This is why we see them on the shorelines and beaches in the warmer parts of the world. They need year round warmth and moisture to grow well and produce fruit.  The Coconut palm tree can grow up to 98 ft tall and has 13-20 ft long leaves. A tree can begin producing fruit as early as 6 years but usually take between 15 to 20 years to reach its peak producing capacity. Most trees produce about 30 fruit a year but under ideal conditions they can produce as much as 75 a year.  Coconuts can be found in more than 90 countries with most of the production coming from tropical Asia.  The Philippines, India, and Indonesia account for over 72% of the production.

Coconuts already have a variety of uses, as food, cosmetics and animal food. Virtually every part of the palm can be used by humans for economic value.

Production of the oils used for biodiesel requires the coconut meat be removed from the seeds, dried and then pressed for the oil. A coconut that is between 12 to 15 months old is best for this.  You can expect to get about 50ml of oil per nut. The remaining meal is then able to still be used as an animal feed or can even be turned into a flour for baking.

 

Coconut Oil as a feedstock for Biodiesel.

Biodiesel Certificate of Analysis for Coconut Oil Chart.

 

 

Coffee Oil

Cup of Coffee on Coffee beans, Can this be the next form of BioDiesel?Coffee comes from roasted coffee beans, these “beans” are actually the seeds from berries of the Coffea species, with the two most common species being C. arabica and C. canephora. People have been drinking coffee since the 15th century.  Coffee plants are evergreen shrubs that can grow up to 15 feet tall. They have glossy, dark-green leaves about 4 to 6 inches long.  Brazil, Vietnam, and Colombia are were most of the coffee is coming from.

Most Coffee grounds are thrown away or used as compost, but if we were to extract the oil possibilities arise. Coffee oil comes from spent coffee grounds; the grounds can contain as much as 11 to 20 percent oil. Extracting the oil doesn’t stop the grounds from being used as compost and you now have an oil that can be converted into biodiesel.  In the past the process of extracting the oil was cost prohibitive and took many steps to complete. There have been some recent advances in this process that could change this in the future. This method, if used on all coffee grounds, could produce over 286 million gallons a year of biodiesel.

 

Coffee Oil and the biodiesel that is produced from it.

Biodiesel Certificate of Analysis for Coffee Oil Chart.

 

Last article for biodiesel feedstocks was Castor Oil and Choice White Grease.

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BioDiesel Feedstocks – Castor Oil & Choice White Grease 1024 721 Star Oilco

BioDiesel Feedstocks – Castor Oil & Choice White Grease

In this post we continue our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. This week’s two feedstocks are Castor Oil and Choice White Grease. For more information and more feedstocks this is the main page of the feedstocks we have examined so far.

Castor Oil

Castor oil comes from Ricinus communis, known commonly as the castor bean plant. While the castor bean is not a real bean, it is called this due to the shape of the seeds.  These seeds consist of about 45-50% oil. Ricinus communis known commonly as Castor Bean plantRicinus communis is a fast-growing shrub type plant that can reach the size of a small tree. This perennial flowering plant is native to the southeastern Mediterranean Basin, Eastern Africa, and India, but grows easily throughout tropical regions. It is not a cold hardy plant, although in a suitable environment it can become invasive.  Castor bean plants are grown as ornamental plants throughout the world and are used extensively as a decorative plant in parks and public areas. The castor bean plan will grow rapidly in a single season, about 6-10’ tall. Ornamentally, it is most valued for its huge, palmately (having four or more lobes or leaflets radiating from a single point) 5-11 pointed lobes, toothed, glossy green leaves (each to 1-3’ across) and round, spikey, reddish-brown seed capsules. Small cup-shaped, greenish-yellow apetalous (lacking flower petals) spikes which are not particularly showy. Different cultivations of the plant result in dwarf and large plants, some with attractive reddish, bronze or purple leaves and bright and colorful flowers. Castor Beans contain about 45-50% oil

An additional benefit of this source of oil is that it doesn’t impact the food supply. The entire plant is poisonous, but has some reported medicinal uses. Other uses of the plant include being used as an insecticide against some ticks and food for silkworms. Castor oil has been used as a lubricant in engines for years, because of the high heat resistance it has historically been used in two-stroke engines.

 

 

 

 

Castor Oil and Bio-diesel sample

Castor Oil biodiesel Certificate of Analysis

Choice White Grease

The US Department of Agriculture defines Choice White Grease (CWG) as “A specific grade of mostly pork fat defined by hardness, color, fatty acid content, moisture, insolubles, unsaponifiables and free fatty acids.”

CWG is similar to beef tallow that we discussed in a previous week. It is an animal by-product, meaning that they are only produced in relation of raising the animal for meat or food production. As we can see from the picture it is a saturated fat and is at least partially solid at room temperature. This means that the resulting B100 biodiesel will have a higher cloud point.  CWG has historically been used as livestock feed. Additionally, using CWG for biodiesel gives pork producers an additional revenue and outlet for the product, helping elevate the return on investment for these farmers.

Choice White Grease and Bio-diesel sample

Choice White Grease biodiesel Certificate of Analysis

 

Last article for biodiesel feedstocks was Algae Oil and Canola Oil.

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BioDiesel Feedstocks – Algae Oil & Canola Oil 1024 721 Star Oilco

BioDiesel Feedstocks – Algae Oil & Canola Oil

This post’s two oils are Algal Oil and Canola Oil.  If you would like to look ahead at some of the other feedstocks that Renewable Energy Group (REG) studied, or if you would like to look a little more in-depth at the comparisons here is the link to the Feedstock and Biodiesel Characteristics Report.   This is the main page of feedstocks we have looked at so far, and last weeks look at Borage Oil & Camelina Oil is here.  B20 Biodiesel (B20 stands for 20% biodiesel and 80% petroleum diesel)  is the drop in solution for reduced emissions in today’s modern diesel engines.  To understand what some of the alternate feedstocks that can be used for biodiesel, we are examining a report that Renewable Energy Group (REG) produced in 2009. All certificates of analysis and results are for B100.

Algal Oil

Algal Oil has a huge potential to be the next source of Biofuel feedstock. Among the many benefits is that algae can be grown in any environment that can contain water, and algae doesn’t carry the negative stigma of using a potential source of food to create a fuel.  In addition, you could use algae to clean up waste water and then use the fats to create the biodiesel. A recent study here is working on that concept. The U.S. Department of Energy has recently invested $2 million dollars into University of Michigan for research into algae as a diesel fuel. (see story here) The goal is to find high yield algae that produce a high grade bio crude for renewable diesel or biodiesel. Here is the YouTube video about the research.

The two diverse samples of crude algal oil, that were used in the report from 2009, were obtained from Solazyme, Inc.  This Company works with algae to produce renewable oils and ingredients for industries. The report doesn’t go into what kinds of algae was used or the process that they used to convert the algae to oil.

Biodiesel Certificate of Analysis for Algae Oil 1 Bio-diesel Certificate of Analysis for Algae Oil 2

Canola Oil

Canola is the seed of the species Brassica napus or Brassica campestris.Canola is the seed of the species Brassica napus Brassica Napus is also known as rape or rapeseed.  The name rape is derived from the Latin word for turnip, rapum.  Brassicaceae is the family of which mustard, cauliflower and cabbage belong.  The name Canola comes from the contraction of Canada and ola, meaning oil.  Developed in 1970s by researchers from the University of Manitoba and Agri-Food Canada, the use of the term Canola means that the oilseed meets certain standards.  The Official Definition of Canola is:

“Seeds of the genus Brassica (Brassica napusBrassica rapa or Brassica juncea) from which the oil shall contain less than 2% erucic acid in its fatty acid profile and the solid component shall contain less than 30 micromoles of any one or any mixture of 3-butenyl glucosinolate, 4-pentenyl glucosinolate, 2-hydroxy-3 butenyl glucosinolate, and 2-hydroxy- 4-pentenyl glucosinolate per gram of air-dry, oil-free solid.”

Government regulation requires Canola oil to to be limited to a maximum of 2% erucic acid these particular samples contains less than two percent erucic acid and the solid component contains less than 30 micromoles per gram of glucosinolates.

According to Reuters, “Rapeseed is the most produced oilseed in the EU.” This trend is gradually shifting to soya beans this article continues to explain. Currently 60 percent of the vegetable oil used in biodiesel comes from rapeseed oil in the EU.

Canola is the seed of the species Brassica napus

Certificate of Analysis from REG for Canola Oil based Bio-diesel

 

 

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BioDiesel Feedstocks – Borage Oil & Camelina Oil 1024 721 Star Oilco

BioDiesel Feedstocks – Borage Oil & Camelina Oil

This post continues our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report.  Different feedstocks give the resulting B100 biodiesel different characteristics.   This week’s two oils are Borage Oil and Camelina Oil.  If you would like to learn more about some of the other feedstocks please visit the main page of feedstocks we have looked at so far.

Borage Oil

Borage oil comes from the plant, Borago officinalis, also known as starflower. Borage officinalis Plant (starflower)The starflower is easily grown in average, dry to medium moisture, well-drained soils in full sun to light shade. In addition this plant tolerates poor soils and drought. It is native to Mediterranean region and is an annual that will continue to propagate itself in a garden by reseeding. The plant grows to 2 to 3 feet tall and the flowers are commonly blue, although pink and white flowers are commonly cultivated.  The flowering season is relatively long from June to September and in milder climates the starflower will bloom for most of the year.

The leaves are edible and the plant is commercially cultivated for its oil.  As a fresh vegetable it is said to have a cucumber-like taste and the flowers have a sweet taste.  It has the highest value of γ-linolenic acid in any readily available specialty oil.

Certificate of Analysis of Borage Oil. Borage Oil sample and Borage Biodiesel sample

Camelina Oil

Camelina oil comes from the plant, Camelina sativa, a member of the mustard family and a distant relative to canola. It is an annual flowering plant that grows well in temperate climates and it also has the common names of gold-of-pleasure and false flax. Camelina SativaThis flowering plant is native to Europe and Central Asian areas. Camelina plants grow from 1 to 3 feet tall, are heavily branched and produce seed pods with many small, oily seeds. Some varieties of camelina contain 38-40 % oil. Camelina can be grown in arid conditions and does not require significant amounts of fertilizer.

According to science direct:

“Camelina is adaptable to many different environmental conditions… Camelina an ideal crop for use on less productive lands and in areas without sufficient rainfall to support other crops. When produced under these circumstances, Camelina would not be displacing crops used for food production and positively addresses the food for fuel debate that often plagues the use of crop oils for fuel production.”

Camelina only requires a short growing season and they are fast growing. In 2009, the Navy purchased 40,000 gallons of jet fuel derived from camelina.

The oil is high in omega-3 fatty acid. This makes the oil great for biofuels and the resulting leftover meal a good option for livestock feed. Other uses for this plant consist of the oils being used in cosmetics, burnt in lamps, and herbal medicine. The seeds are edible and can be eaten raw in salads or mixed with water to create an egg substitute.

 

Camelina Oil Chart - Certificate of Analysis Camelina Oil and Camelina BioDiesel

 

Next weeks biodiesel feedstocks are Algae Oil and Canola Oil.

Bio-diesel and Feed-stock samples at REG
What Types of Feedstock Can Be Used To Make Biodiesel? 700 525 Star Oilco

What Types of Feedstock Can Be Used To Make Biodiesel?

To answer what feedstocks can be used to make biodiesel we need to first answer – What is Biodiesel?

Biodiesel is created through a process called transesterification.  Transecterification is when an alcohol such as methanol or ethanol is added to an oil or fat.  This creates methyl esters and glycerin.  Methyl esters is the scientific name of Biodiesel.  Because biodiesel needs a fat or an oil to start with, this fuel can can be created with any number of feedstocks.  If you would like to learn more about Biodiesel check out this for more questions about biodiesel.

According to the U.S. Office of Energy Efficiency & Renewable Energy:

“A feedstock is defined as any renewable, biological material that can be used directly as a fuel, or converted to another form of fuel or energy product. Biomass feedstocks are the plant and algal materials used to derive fuels like ethanol, butanol, biodiesel, and other hydrocarbon fuels. Examples of biomass feedstocks include corn starch, sugarcane juice, crop residues  such as corn stover and sugarcane bagasse, purpose-grown grass crops, and woody plants. “

Renewable Energy Group (REG) performed a study in 2009 with the support of the Iowa Power Fund Board and the Iowa Office of Energy Independence that tested 36 individual feed-stocks.  Star Oilco will be spotlighting these feedstocks through our blog and our social media. The full report can be found on their site if you would like to read ahead or explore the results in more depth. We hope you find these as interesting as we did!

Bio-diesel and Feed-stock samples at REG

Above photo taken at REG headquarters in Ames, Iowa.

This first blog highlights the following 2 types of feed-stock:

Babussa Oil & Beef Tallow

Babassu Oil

Attalea speciosa

Babassu oil is extracted from the seeds of the babassu palm tree, Attalea speciosa, an evergreen tree growing to 30 m (98ft) by 20 m (65ft) at a slow rate. It is hardy to zone (UK) 10 and is not frost tender. The flowers are pollinated by bees and other insects. The tree is common in Brazil, Mexico, and Honduras; it grows well in areas typically cultivated for coconut or palm. The kernels contain 60-70% oil, appear transparent, and smell like walnuts. In its natural form the oil is liquid at 20-30°C (68 – 86°F). The seeds are edible and the oil is used in margarine, soaps, detergents, lamp oil and skin products. Oil extraction results in a cake containing 15-25% protein (depending on the shell content), which is a valuable feedstuff.

In February 2008, Babassu palm oil and coconut oil were blended with jet fuel to power a Virgin Atlantic Boeing 747 during a test flight from London’s Heathrow to Amsterdam.

Babassu oil is extracted from the seeds of the babassu palm treeBabassu Oil Chart

Beef Tallow

Tallow is a rendered form of the waste fats and greases from processing beef. Rendering is a process by which lipid material is separated from meat tissue and water under heat and pressure. Beef tallow is primarily made up of triglycerides and it is solid at room temperature. The B100 that is created from this source has a very high cloud point. “Cloud point is the temperature at which wax (paraffin) begins to separate when oil chilled to a low temperature, and it serves as an important indicator of practical performance in automotive applications in low temperatures.”  (Source)  The other uses for tallow include animal feed, soap, cooking and in the past, candles.

Beef Tallow Animal tissue is converted to tallow using rendering; a process by which lipid material is separated from meat tissue and water under heat and pressure.Beef Tallow Chart

 

Article 2 Feedstock : Borage Oil & Camelina Oil

Article 3 Feedstock : Algae Oil & Canola Oil.

Article 4 Feedstock : Castor Oil and Choice White Grease

Article 5 Feedstock : Coconut Oil and Coffee Oil

Article 6 Feedstock : Evening Primrose Oil and Fish Oil

Article 7 Feedstocks : Hemp Oil & High IV and Low IV Hepar

Article 8 Feedstocks : Jatropha Oil, Jojoba Oil, & Karania Oil

Article 9 Feedstocks : Lesquerella Oil & Linseed Oil

Article 10 Feedstocks – Moringa Oil & Neem Oil

Article 11 Feedstocks – Palm Oil & Perilla Seed Oil

Article 12 Feedstocks – Poultry Fat & Rice Bran Oil

Article 13 Feedstocks – Soybean Oil & Stillingia Oil

Article 14 Feedstocks – Sunflower Oil & Tung Oil

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Oregon Biodiesel and Ethanol Fuel Mandates 1024 640 Star Oilco

Oregon Biodiesel and Ethanol Fuel Mandates

Oregon Biofuel Blending Requirements for Gasoline and Diesel.

Oregon law has a 5% Biodiesel and 10% Ethanol fuel blend mandate.

In Oregon, you can expect to buy a biofuel with every gallon of gas or diesel, whether you are buying at a retail pump or commercially delivered bulk fuel. Unless you are expressly seeking out a ethanol-free premium unleaded or off road heating oil expressly free of biodiesel, you can expect the fuel will have a low carbon blend of biofuel in it.

Why does Oregon have biofuel blended in every gallon of fuel?

There are several layers of rules, requirements, and incentives placing a minimum of 5% biodiesel blend in diesel and a 10% ethanol blend in gasoline. The City of Portland’s Bureau of Development Services provides information and resources on the background of both Portland and Oregon’s requirements.

Oregon state has a 5% blend mandate for all diesel fuels sold statewide. Portland has its own standard of for 5% biofule in diesel, which is slightly different but functionally the same as the states. Oregon’s standard requires B5/R5 if it’s sold into  machinery (dyed off road or clear on road diesel), which requires a 5% biofuel component. In the  formation of this Oregon statewide mandate, renewable diesel was considered acceptable.

Oregon also has a 10% ethanol blend mandate for all gasoline fuels with a few exceptions. Portland has this same rule as it mandated ethanol blends prior to Oregon state. Oregon has exceptions for ethanol-free premium unleaded.  (Warning: the City of Portland has no exemption for non-oxygenated premium fuels) though there are some sellers of it. Oregon state’s exceptions being premium gasoline for aviation and non-ethanol premium gasoline sold at retail gas stations. This was adopted later after the initial Renewable Fuel Standard mandates. Portland did not follow Oregon with this flexibility for small engine or classic car enthusiasts seeking non-ethanol fuel.

The rules that drive biofuel use in Oregon’s fuel:

The City of Portland has its own Renewable Fuel Standard (RFS) which is seen in Portland City Code Chapter 16.60 Motor Vehicle Fuels. This RFS requires all diesel sold (either commercial or retail fuel) to contain a minimum 5% biodiesel (specifically methyl-ester molecule). The RFS also requires all gasoline sold (either commercial or retail gas stations) to contain a 10% blend of ethanol. In addition to this fuel blend requirement, Portland also has requirements for the original feedstock biodiesel is made from. Portland requires that 50% of the biodiesel feedstock be sourced from recycled vegetable oil, canola oil, and a few other types available in the Pacific NW.

The State of Oregon has its own Renewable Fuel Standard. It is less restrictive than Portland’s, allowing renewable diesel or biodiesel to meet its 5% blend requirement. You can find the law in Oregon Revised Statute 646.922. The Oregon RFS also requires a 10% ethanol to be blended with gasoline. There is an exception for premium gasoline to be ethanol-free.  This fuel is commonly called “Non-Oxy Premium” or “Clear Premium” by those seeking to order it.

If you want more information on successfully using Biodiesel and Ethanol in your fleet.

If your fleet is seeking to succeed with biofuels, here are some great resources to learn more about biodiesel, ethanol,  and renewable diesel fuels.

If you have questions about biofuels, Star Oilco can help. Do not hesitate to reach out if you have questions, even if you are not in our market. We want you to be successful in your fleet.  We are here to help.

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oregon-made-biodiesel
Oregon-Made Biodiesel 1024 819 Star Oilco

Oregon-Made Biodiesel

Low CO2 Biodiesel Made from Waste Vegetable Oil in Salem, Oregon.

B20 Biodiesel A PROVEN FUEL

Star Oilco is a proud seller of locally-sourced biodiesel products.

We believe in biodiesel and run B20 in our own fleet. Star Oilco has been a pioneer in successful fleet demonstration of B20 and blends up to B99 in a host of applications for over a decade. There is no lower cost way to reduce your CO2 emissions than by substituting petroleum diesel with a recycled vegetable oil feedstock biodiesel blend. It is a drop in solution that requires awareness in your fleet maintenance concern — but beyond that is a very low barrier to use.

We have worked with our vendor for recycled oil biodiesel, SeQuential Biofuels, since 2004.

SeQuential Biofuels collects feed stocks collected from deep fryers and food processors throughout the Pacific Northwest to make the lowest CO2 biodiesel fuel in Oregon. If you are seeking to reduce your carbon footprint, biodiesel is your drop in solution. Ready and approved by every manufacturer for on- and off-road vehicles at a 20% biodiesel blend.

How can we help you move forward?  

We are here to help you be successful with biodiesel, even if you are not our customer. Let us know if you have questions or if we can be of help.

Simply call us at 503-283-1256 or contact us using the form below.

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What Are Diesel Soaps? Do Diesel Soaps Cause Some Diesel Engine Problems? 1024 585 Star Oilco

What Are Diesel Soaps? Do Diesel Soaps Cause Some Diesel Engine Problems?

Star Oilco answers: What are Diesel Soaps?

Cliff Burbrink, chemical technology specialist at Cummins Filtration, provides a layman’s definition of diesel soaps:

“Diesel soap is not very different chemically than the soap used to wash your hands. The main ingredient in a bar of soap is formed when lye reacts with fats or oils. Lye is sodium hydroxide.

Fats and oils contain fatty acids. When they react, they form sodium soaps. Diesel soaps are formed from acidic additives in the fuel [such as some corrosion inhibitors and lubricity improvers] reacting with trace amounts of sodium.”

 

Rick Chapman, Industry & OEM Liaison Manager, Innospec Fuel Specialties, adds that acids can be derived also from other sources:

“[Soaps] can also be formed from free fatty acids in biodiesel starting materials and carboxylic acids derived from oxidatively degraded fuel and/or biodiesel.”

 

From a layman’s point of view, then, the formation of diesel soaps is the result of metals, such as sodium, calcium and potassium (in the form of positively charged ions, or cations), reacting with various sources of acid in the fuel.

 

“When these two species [acidic compounds and cations (usually sodium)] come together, diesel soap can form,” says Chapman.

“There are a lot of other factors or variables that can play into it, of course, such as pH, solubility, mixing intensity and so forth—but this is the basis for it. Unfortunately, when these soaps form, assuming they are formed from additives, they make the corrosion inhibitor or lubricity improver inert, and the corrosion or lubricity protection provided by the additive is lost.”

 

 

 Diesel soaps

 

  1. Plug fuel filters
  2. Form injector deposits that lead to over-fueling
  3. Create Turbocharger problems
  4. Generate Oil dilution
  5. Cause Poor performance, and poor fuel economy

 

In a May 2013 report, “Case Study—Impact of Poor Diesel Fuel Quality on an Urban Fleet,” Cummins Filtration investigated problems with diesel engines in a New York City bus fleet.

Complaints ranged from an excessive number of turbocharger fault codes to smoke at start-up to fuel-injector failures. The investigation uncovered excessive soot deposits in the turbocharger, resulting from over-fueling, which was determined to be the result of fuel injectors sticking because of deposits that were “rich” in the metals of sodium and calcium.

Although injectors showed sign of scuffing—the result of hard particle contamination, which, says the report,

“is the greatest fuel quality concern for high-pressure/common-rail fuel systems, worldwide”

—investigators determined that scuffing was not the primary issue for the immediate problems the bus engines were exhibiting.

The culprits in this instance were “metal carboxylates” in the fuel, more commonly know as “diesel soaps.” The recommended fix for the problem was use of a fuel additive that could both clean the Injectors and minimize further deposits, coupled with much tighter filtration.

 

Another Bad Actor

 

 

 

Biofuel is manufactured by reacting a plant-derived fat or oil (usually soybeans in the United States) with an alcohol, using sodium hydroxide as a catalyst. An unwanted by-product of the process is glycerin.

Although most of the glycerin is washed out during the manufacturing process, regulations do allow 200 ppm to remain.

Biofuel usually is mixed with petroleum diesel in 5-, 10- or 20-percent concentrations to form biofuel blends, but even at these relatively low concentrations, enough glycerin remains to create filter-plugging problems when, under certain fuel moisture and temperatures conditions, it becomes a solid and drops out of solution.

To help counteract glycerin’s effects, Jim Peterson, sales manager for Donaldson’s Hydraulics and Clean Solutions Group, suggests these measures:

  • Filter fuel on the dispensing side of the bulk tank and use proper on-machine filters
  • Keep fuel dry with proper tank flushing and proper breathers
  • If possible, moderate the temperature of stored fuel above the glycerin dropout level
  • Turn over fuel as quickly as possible
  • Keep fuel infrastructure as free from particulate contamination as possible
  • Ask OEMs about using detergent additives to keep glycerin in solution, both in equipment and bulk storage

 

Filtration and Additives

 

 

 

As noted before, the contamination of diesel fuel with soaps is not as prevalent, at least in many fleets, as other sources of fuel contamination.

These other fuel contaminates include hard particulates, increased water in biofuel blends, rapid oxidation of such blends, microbial growth, so-called asphaltenes (compounds that can agglomerate into an oily sludge), acetic acid formation and glycerin.

Glycerin being an unwanted by-product of biofuel manufacturing. “There are so many inherent problems with diesel fuel today,” says Hydrotex’s Cummins, “that machine owners must take a holistic approach when attempting to resolve them.”

The best defense against diesel soaps (and for most other contaminants, as well) seems to be the use of premium filtration, like the “Donaldson clean & Dry kit which includes 4 micron particulate and water filters. The kit also incorporates a desiccant breather to absorb moisture.”

Donaldson Clean and Dry Filter kit

In addition, (tank intake, tank dispensing, and on-machine), good tank housekeeping, and a well-chosen additive package.

Additives might be included in “premium” diesel fuel offered by some jobbers, but solving a serious soap problem might require consultation with an additive supplier who can take a comprehensive, laboratory-assisted view of all the fuel-quality issues in a particular fleet.

But, the best efforts are no guarantee of complete success when dealing with diesel soaps.

We’ve seen soap deposits form in engines that use our most effective filters—those proved to remove 99.9 percent of material 4 microns and larger and significant amounts of material smaller than 4 microns,”  says Cummins Filtration’s Burbrink.

“If soap particles don’t agglomerate before the filter, they can pass through it. When they hit the injectors, the heat can cause these particles to deposit on metal.”

 

Deposit control

 

 

 

“We have seen great success with some additives,” says Burbrink. “The use of good detergents has dropped the failure rate significantly in some applications. Unfortunately, we also have seen customers having issues even though they are using detergents.”

That said, a well-formulated additive package seems to be an integral part of the potential resolution of problems with diesel soaps.

A good, multi-functional package will contain corrosion inhibitors and lubricity improvers (some formulations use nonacid, non-reacting lubricity improvers), as well as a deposit-control agent that will assist in cleaning injectors and minimizing further deposits.

 

The Key

 

 

 

“The key to diminishing field issues is the use of a two-prong strategy,” says Innospec’s Chapman. “One, use an additive that provides the required lubricity but is resistant to reaction with metal hydroxides, and, two, use a deposit-control additive to ‘clean up’ and ‘keep clean’ any deposits that may form, regardless of the their source. Deposit-control additives are useful for reducing injector deposits, reducing filter plugging, and for carrying through trace amounts of water. In lower-dose rates, or at a ‘keep-clean’ level, they will put a protective coating on metal surfaces and not allow deposits to form—or will limit their formation.”

Hydrotex’s Cummins makes the point, too, that treatment rates for additives, a corrosion inhibitor, for example, might have to be adjusted to meet the conditions of a particular storage tank. Cummins also reminds machine owners that deposit-control additives might need time to work in certain situations: “Soap deposits can get very deep into the injectors, become sticky, and cause poor actuation of the pintle. A good additive package will help clean the injectors, but given the nature of the deposits, it’s usually not a quick fix. The process might require four or five tanks of treated fuel before improvement is noticed.”

Sunrock’s Dennis offers this suggestion to fellow fleet managers: “I would recommend that fleet managers, if they haven’t already done so, educate their fuel suppliers on the subject of upstream fuel-contamination issues and their effects on diesel engines.

Managers can use that opportunity to register their concerns about diesel soaps—for the purpose of promoting a partnership in utilizing countermeasures against diesel-fuel contamination. Their fleet reliability depends on it.”

 

 

To read more technical data on Diesel Soap click link below

SOAP AND GLYCERIN REMOVAL FROM BIODIESEL