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Adam Maxon

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Biodiesel Feedstocks – Poultry Fat & Rice Bran Oil 1024 721 Star Oilco

Biodiesel Feedstocks – Poultry Fat & Rice Bran Oil

Looking further into biodiesel feedstock we continue with Poultry Fat and Rice Bran Oil in our deeper dive into the feedstocks that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. If you would like to see more you can  read more here about the feedstocks we have examined in the past.

Poultry Fat

Rendering is the process of turning the left over animal products into fat or tallow. After the common parts of the animal are harvested the remaining parts are ground up and cooked. The oil and fat is then separated from the protein solids. Poultry fat, commonly made from chicken, Poultry Fat a possible source of bio-dieselis different from other forms of fat and tallow.  It tends to have less saturated fat. According to Farm Energy:

“Beef tallow and pork lard are typically about 40% saturated (sum of myristic, palmitic and stearic acids). Chicken fat is lower at about 30-33%. For comparison, soybean oil is about 14% saturated and canola oil is only 6%. Thus, tallow and lard are usually solid at room temperature and chicken fat, while usually still liquid, is very viscous and nearly solid.”

The high content of saturated fat can be a draw back for biodiesel produced from animal products. Beef Tallow in this study produced B100 (100% biodiesel) with a cloud point of 16° C or 60.8° F.  The Poultry Fat B100 in this study had a cloud point of 6.1° C or 42.98° F, in comparison Soybean Oil B100 in the same study was 0.9° C or 33.62° F.

One of the benefits of using animal fats for biodiesel is a higher Cetane number. (Source) “cetane number is a measurement of the quality or performance of diesel fuel. The higher the number, the better the fuel burns within the engine of a vehicle.”  Petroleum based fuels have a cetane number between 40 -44, soybean based biodiesel is between 48 – 52 and animal fat based biodiesel can have values over 60. (Source)

Poultry Fat Feedstock and Bio-Diesel

Poultry Fat Certificate of Analysis

 

 

Rice Bran Oil

Rice bran oil is a vegetable oil which is greatly available in East Asia countries. It is a byproduct of rice processing, containing about 15-23% oil.  The Rice Bran Oil that was used in this study was refined, bleached, deodorized, winterized (RBDW).

Rice bran oil is similar in make up to peanut oil made up of monounsaturated, polyunsaturated, and saturated fatty acids.

While the Oil is this study was considered non-edible, when processed in other ways the oil can be used in cooking and is popular for Asian countries such as Bangladesh, China, India and Japan.

Rice Bran Oil - Feedstock and Bio-Diesel

Rice Bran Oil Certificate of Analysis

 

Last article for biodiesel feedstocks was – Palm Oil & Perilla Seed Oil

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Biodiesel Feedstocks – Palm Oil & Perilla Seed Oil 1024 721 Star Oilco

Biodiesel Feedstocks – Palm Oil & Perilla Seed Oil

This deeper look into biodiesel feedstock includes one that is very controversial – palm oil. We will also be covering perilla seed oil as we continue our look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. Read more about the feedstocks we have examined in the past.

Palm Oil

Palm oil is produced from the fruit of oil palms such as the American oil palm Elaeis oleifera, the maripa palm Attalea maripa, and most commonly the African oil palm Elaeis guineensis which is originally native to the area between Angola and the Gambia. This plant is different than the coconut oil that that comes from Cocos nucifera. (Read here for more information about coconut oil as a feedstock.) The E. guineensis can grow between 60 – 90 feet high with a single stemmed palm tree. Fruits are ovoid-oblong drupes, ¾ inch –2 inches long, tightly packed in large bunches with 1000–3000 fruits (Source).Oil palm plantation on the slopes of Mt. Cameroon

The natural state of palm oil as a saturated fat, is slightly reddish and semisolid at room temperature. For every 225 lbs. of fruit bunches, typically 50 lbs. of palm oil and 3.5 lbs. of palm kernel oil can be extracted. Based on the picture of the sample, we can assume that this source has been refined, bleached and deodorized to remove the beta-carotene that gives it the reddish color the natural state of palm oil.

Palm oil is edible and is used as a cheap substitute for butter and other vegetable oils. In fact, palm oil is in about half of all packaged products that are sold in supermarket, and not just in the food, but in things like soaps, cosmetics, and detergents. The controversy over palm oil is where it is grown and how the farmland is acquired. The main culprit is the African palm oil tree. It has been introduced and grown in Madagascar, Sri Lanka, Malaysia, Indonesia, Central America, the West Indies and several islands in the Indian and Pacific Oceans.

The problem that arises is rainforests are being cut down and replaced with this profitable crop. The incredible diversity of the rainforest is replace with a single species, and this has led to reductions in animal habitats such as orangutans, elephants, rhinos, and tigers (Source). If you would like to know more follow some of the links that were supplied as sources.  As far as green house gases and the reduction of them a recent study by the University of Göttingen investigated the whole life cycle of the greenhouse gases and here are the results (Source):

“The researchers found that using palm oil from first rotation plantations where forests had been cleared to make way for palms actually leads to an increase in greenhouse gas emissions compared to using fossil fuels. However, there is potential for carbon savings in plantations established on degraded land. In addition, emissions could be reduced by introducing longer rotation cycles or new oil palm varieties with a higher yield. “

The other side of this argument is that the production of this oil is a lifeline for some countries. Malaysia and Indonesia alone employ 4.5 million people directly in the industry with millions more depending on palm oil production indirectly for employment (Source). Stopping the use of palm oil would endanger many of these people.

Palm Oil and Palm Oil Biodiesel

 

 

 

 

 

 

 

 

 

Biodiesel - Palm Oil Certificate of Analysis

 

 

Perilla Oil

Perilla oil comes from the plant Perilla ocymoides, a synonym for the more common name Perilla frutescens. Perilla frutescens var. japonica in Gimpo, KoreaIt is native to India and China in the mountainous regions and cultivated in China, Korea, Japan, and India. Introduced varieties of this plant are considered a weed in the United States and go by the common names Chinese basil, wild basil, perilla mint, beefsteak plant, purple perilla, wild coleus, blueweed, Joseph’s coat, and rattlesnake weed. This herb grows easily unattended, but is toxic for cattle and horses.

This annual herb is 1 ft to 6 ft tall with a square stem and green or purple minty smelling leaves. The plant takes about 4 months from germination to start flowering, and the seeds mature about 6 weeks after.

The flowers, leaves, seeds, and sprouts are all used in Japanese, Korean, and Vietnamese foods either as flavoring or a garnish. According to Pl@ant Use:

“Perilla serves as a side dish with rice and as an important ingredient in noodles, baked fish, fried foods, cakes and beverages. The leaves can be easily dried for off-season use. The purple-leaved forms, which contain large amounts of anthocyanins, are used for coloring pickled fruits and vegetables. These forms are also very decorative ornamental plants.”

While mostly used as a food, the plant is also used for an antidote for fish and crab meat allergies in Japan and has some potential as an anti-inflammatory and anti-allergic reagent.

The seeds contain 35-45 percent oil. In addition to being made into biodiesel, this oil is also used for perfumes and sweetening agents.

 

Perilla Oil and Perilla Biodiesel

Perilla Oil Certificate of Analysis

 

Last article for biodiesel feedstocks was Moringa oleifera Oil and Neem Oil

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Top 4 Reasons Hotels Should Use Pacific Pride 1024 688 Star Oilco

Top 4 Reasons Hotels Should Use Pacific Pride

Pacific Pride Fuel Cards for Airport, Hotel, or Travel Shuttle Companies

Fuel for shuttle vans through Pacific Pride

Control your fuel spending with fuel card management, emailed receipts, transparency, and accountability for your hotel or travel shuttle bus drivers.

Star Oilco is an independent Franchisee of Pacific Pride

Pacific Pride Fuel cards for Shuttle Drivers

Running a shuttle service for a hotel for any reason can have a lot of moving parts:

  • Hiring
  • Training Drivers
  • Scheduling Shifts
  • Keeping the Vehicles Full of Fuel
  • Ensuring a Consistent Time Table

Let Star Oilco track and control the fueling for you. We can save you money and significantly reduce your risk of fuel theft while getting your drivers out of lines at a retail gas station. In addition, our locations are open even on holidays or late at night.

Shuttles going to and from the airports can be on tight schedules and  don’t have a lot of time to fuel. Meeting your guests’ needs means you can’t have your drivers in lines for a long time. Stand-alone commercial-only Pacific Pride and CFN sites in the northwest are a real resource for your business. Many stations are located near airports. They speed up the labor associated with fueling and significantly lock down the chance for fraud or theft when using your fuel card. Stand-alone sites limit access to convenience store items so employees won’t be tempted to spend time browsing and make purchases on the company credit card.

With Pacific Pride and CFN stand-alone commercial cardlock sites, there are other benefits beyond just the convenience. The biggest difference is that these commercial cardlock sites are built with security in mind. Retail stations are engineered to sell as many products as possible to those pulling up for gasoline. Commercial cardlock sites are designed for commercial users who seek the fastest fueling experience. That is a major contrast between the two.

Top 4 Reason Hotels Should Use Fuel Cards

Top 4 Reason Hotels should use Pacific Pride Fuel Cards

Reason #1 – Better Tracking and Management

With a myriad of responsibilities required of those who run hotels or shuttles, simple methods to control when, where, and what is purchased any time during the day can save time and money. Controls keep fuel purchases in line and by only those with authorization.

WHEN: If the drivers only need access to fuel during specific shifts you can set the cards to work only during these times.

WHERE: Drivers can be limited to specific locations such as only Pacific Prides, or if more flexibility is needed, they can be authorized to use any of the 57,000 extended network locations. Pacific Pride locations are also open 24/7 and open even on the holidays.

WHAT: Drivers can be limited to specific types of fuel. If the van takes diesel you can set the card to only have access to diesel. These simple strategies can eliminate many of the issues that can arise when fueling.

Talk to a Card Lock expert at Star Oilco to find out more. 

 

Reason #2 – No More Paper Receipts 

Tracking and reviewing receipts takes up a lot of time. Pacific Pride fuel cards can be set up to automatically email every time a fueling occurs. Using a fuel card eliminates the need to continuously organize and track expense receipts from drivers. No more going through each and every receipt to see what and how much was purchased. Fuel can be set up to see which vehicle was fueled, who fueled it and when it was fueled. These transactions are easily organized with entered mileage and fuel costs in the bills that are issued twice a month. This alone can save hours of labor for accountants and controllers as they audit the bills.

Reason #3 – Stop Fuel Theft

By using a fuel card, a hotel insures the security of their shuttles and prevents theft by its drivers. This instills peace of mind, as managers know their drivers cannot use a fuel card for personal usage. Fuel cards can be assigned to vehicles and each driver has their own individual PIN#. With a quick email or phone call, card access can easily be granted or blocked as drivers leave or new ones are added.

Reason #4 – Transparency and Accountability

Star Oilco has created a template agreement for drivers to sign as they are assigned identification numbers for the cards. This form helps the driver understand that they are responsible for any unauthorized purchases with their DIN (Driver Identification Number). Setting up emails that are sent in real time can be done so that any unauthorized use can immediately be investigated.

Need to lock down your gas card from fuel theft?

Call Star Oilco, we make it simple.

Our motto is “Keep it Simple” and we make this easy. Feel free to reach out and see what Star Oilco can do for your fleet to upgrade its fleet fueling security.

What do you need to get a fuel card in Oregon?

All you need in order to access Pacific Pride sites in Oregon is a business license and proof that you use over 900 gallons of total fuel a year. CFN commercial cardlock sites have the same requirements. If you are a business using a commercial quantity of fuel, you qualify to self-serve gasoline and you can stop paying your employees to shop at the most expensive retail gas stations with the best mini-mart selection. Instead, get them back on the road 24-7 and usually without a line to wait in.

What do you need for fueling cards in Washington or any other state?

If you drive into Oregon and want to use gasoline, you still need the same requirements as stated above. If you don’t need access to Oregon gas stations, it is much easier to get a fuel card.

 

Star Oilco is an independent Franchisee of Pacific Pride

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Diesel storage tanks UL-2085 needed for modern Fire Code 1024 683 Star Oilco

Diesel storage tanks UL-2085 needed for modern Fire Code

What is required to install a fuel tank in Oregon?

A Tank that meets International Fire Code is a 2 Hour Fire Guard labeled tank.

In recent years Oregon and Washington have been moving to International Fire Code as their adopted standard. Following California with this higher standard of safety as it relates to liquid fuels.  The new standards are far more involved in their construction and therefore their installation as well. Heavy and far more expensive is the most notable standard of a modern Fire Marshall approved tank.

UL 142 – Double Wall Tanks

The old standard for diesel storage was UL-142 (commonly referred to as double wall or “diked tanks” by fleet managers).  These tanks are still made and extremely common throughout the US. If you see one of these tanks for sale and it looks like a great deal it’s probably because of an upgrade requirement causing them to sell it.  Be aware to check code in your local jurisdiction. These tanks still have a wide market for use especially for agricultural zones as well as temporary use with construction sites.

UL 2085 – 2 Hour Fire Guard and Double Wall Tanks

The new standard for storing diesel for refueling vehicles is the UL-2085. This code has been around for gasoline, it is only new in the way that Fire Marshall’s and local municipalities will require it for diesel fuels.

This standard has been around for a long time but typically was used when storing gasoline or more flammable liquids. That standard now applies to diesel fuels as well if they are being installed to refuel equipment, trucks or any other service.  Its worth noting that boilers, HVAC oil furnaces, and other plumbed stationary applications can still use the UL-142 code. Similarly agricultural use in Oregon is allowed a UL-142 use in most applications.  But for fleet fueling even if only a 100 gallon tank the Fire Marshall’s new standard is the UL-2085 concrete lined fire guard tank. It is also worth noting that if you have an installed UL-142 tank in a commercial or industrial zoned property you probably are okay with grandfathered use. But if you want to change anything the Fire Marshall and local Code Enforcement are going to be looking at the newer and safer standard.

Ask your local Fire Marshall to be sure of what the requirements are.

When discussing diesel storage tank options with your local Fire Marshall it helps to see the reason they have the standards they demand. Also be aware of other requirements that local jurisdiction may have. For instance Portland, Oregon’s Bureau of Environmental Services will often demand a cover be placed over the fueling area, an engineered concrete pad beneath it, as well as a potential oil water separator.  Usually there can be an additional permit and process associated with a tank install to meet the needs of a local Fire Marshall as well.

Two hour fire guard or UL-2085 rated tanks are the new standard in Oregon as we have adopted the International Fire Code. and the picture below says a thousand words. It will protect your property from a lake of fire preventing your diesel fuel from feeding disaster.

This is a great picture of a tank being tested for a two hour fire rating by a vendor of Star Oilco’s. Its speaks to why and what is the concern of your local regulator.

Modern Weld Company is a tank manufacturer out of California that makes great tanks to order exactly perfect for your site.

As they make what you need to the specifications you need you can make the Fire Marshall, local City Code enforcement, and your CFO happy at the same time.  If you have questions about installing a bulk diesel fuel tank to either UL-142 or UL-2085 standards give Star Oilco a call. We can help you meet UL codes for diesel, gasoline, biodiesel, or other storage needs.

biodiesel-feedstocks-caster-oil-and-cwg
Biodiesel Feedstocks – Moringa Oil & Neem Oil 1024 721 Star Oilco

Biodiesel Feedstocks – Moringa Oil & Neem Oil

We’re continuing our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. This posts two feedstocks are Moringa oleifera Oil and Neem Oil.  To see more of the feedstocks we have already covered follow this link to the main page of feedstocks we have examined so far.

Moringa oleifera Oil

Moringa oleifera is a tree with the common names moringa, drumstick tree, horseradish tree and ben oil tree.The tree and seedpods of Moringa oleifera in Dakawa, Morogoro, Tanzania. This tree ranges in height from 15 to 30 feet tall, and is native to India, Africa, Arabia, Southeast Asia, the Pacific and Caribbean islands, South America, and the Philippines. This deciduous tree is fast-growing and drought-resistant. It loves sun and heat and doesn’t tolerate freezing weather. Moringa oleifera is a slender tree with drooping branches, brittle stems and whitish-grey corky bark. It has feathery green to dark-green foliage tripinnate leaves and yellowish-white flowers. The trees usually begin producing about second year about 300 pods, but it can take a few years to get to the 1000 or more pods a good tree can yield.

There are a vast amount of uses for this tree. According to Purdue University, almost every part of the plant has value as a food. The seeds can be eaten like a peanut, the roots can be eaten and taste like horseradish, and the leaves are eaten in salads, curries and used for seasoning.

The plant has other non-food uses include Moringa seeds being pressed for oil. This oil is used in arts and lubricating small and delicate machines, and it clear, sweet and odorless it is edible and is also used in manufacturing perfumes and hair products. The wood can be used to create a blue dye and the bark is used in tanning.

The oil from the seeds contain between 33 and 41 % oil. It is also known as Ben Oil, due to its content of behenic (docosanoic) acid. This oil can be used in the production of biodiesel, (Source) and the remaining seed cake can be used as fertilizer.

Morigna Oil and Morigna Biodiesel

Morigna oleifera Biodiesel Certificate of Analysis

 

 

Neem Oil

The Neem tree is also known as nimtree, Indian lilac, or margosa tree. ABHIJEET (photographer) (2014, September 19) Neem tree in banana farms at Chinawal, India. The scientific name is Azadirachta indica. This large evergreen tree that is usually 49 to 66 ft tall but can get as big as 130 ft tall. This fast growing  tree is found in India, Pakistan, Sri Lanka, Burma, Malaya, Indonesia, Japan, and the tropical regions of Australia. It has long skinny leaves that are dark green in color and produces white fragrant flowers. The flowers produce a smooth olive like fruit. The seed in the center is called the kernel which contain 40-50% of an acrid green to brown colored oil.  The oil in the REG study was pure, cold pressed neem oil that was purchased from The Ahimsa Alternative, Inc.

This tree can tolerate high to very high temperatures but does poorly in temperatures below 40o F.   It grows best in dry, sandy well-draining soil. (Source)  Neem trees are drought resistant, but begin to lose leaves in prolonged droughts. The tree propagates itself by seeding and in some non-native environments the plant has been classified as a weed.

There are many uses of the Neem tree. The wood is strong and durable, the tree is related to the mahagony family, so furniture and other durable good can be made from the wood.  The leaves are dried and used in cupboards as an insect deterrent to prevent insects from eating clothes and rice. The trees oil and products can be found in shampoos, soaps creams, toothpastes and mouthwashes. The young twigs are even used as toothbrushes in rural areas. (Source)   The oil extracted from the seeds are used as a natural insecticide, repellent and fungicide. The oil is also used as a lubricant, lamp fuel and can be turned into biodiesel.

Neem Oil & Neem Biodiesel

NEEM Biodiesel Certificate of Analysis

 

Last article for biodiesel feedstocks was Lesquerella Oil & Linseed Oil.

biodiesel-feedstocks-caster-oil-and-cwg
Biodiesel Feedstocks – Lesquerella Oil & Linseed Oil 1024 721 Star Oilco

Biodiesel Feedstocks – Lesquerella Oil & Linseed Oil

We’re continuing our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. This posts two feedstocks are Lesquerella Oil & Linseed Oil.  Here is a link to the main page of feedstocks we have examined so far.

Lesquerella fendleri Oil

Lesquerella fendleri, also known as Physaria fendleri, is part of the mustard family. (Lesquerella) Physaria Fendleri part of the mustard familyThe common names of this plant are popweed and Fendler’s bladderpod. This silvery-gray perennial has four-petaled yellow flowers that grow on a plant that is about 1 to 16 inches tall. Found in plains and mesas in the southwestern United States, it requires low water usage and is one of the first of the flowering wildflowers in the spring (Source).

Lesquerella produces hairless capsules called siliques which contain 6 to 25 seeds. These seeds contain 20-28% oil with around 62% lesquerolic acid. Lesquerella oil is a source of hydroxyl unsaturated fatty acids, and is useful as a replacement for castor oil in some applications.

While there are benefits from using this seed oil, the dark reddish-brown color of the oil is a potential limiting factor. Potential selective breeding and domestication of the plant may solve this issue, but there haven’t been much momentum at this time. That being said, there have been some studies about growing this plant for its oil and the natural gum in its seed coat for commercial use.

 

Lesquerella Oil and Lesquerella Biodiesel

Lesquerella BioDiesel Certificate of Analysis

 

 

Linseed Oil

Linseed (Linum usitatissimum) is also known as flax in North America. The plant is an annual and can grow in large range of climates. Linseed Oil and SeedsFor example, it grows in Argentina, India, and Canada. Linseed oil has been traditionally used as a drying oil. According to REG report, these seeds contains 37-42% oil. The crude oil contains 0.25% phosphatides, a small amount of crystalline wax, and a water-soluble resinous matter with antioxidant properties.

As one the earliest cultivated field crops in the US, it has found many uses for its oils. Linseed oil can be used as a varnish, pigment binder or to manufacture linoleum. These applications have seen reductions in use due to synthetic options that resist yellowing. Other uses for this plant are as nutritional supplements and foods, although raw linseed oil can become rancid unless refrigerated.  After the oil has been pressed out of the seeds, the leftover residue makes great animal food.

As some of the traditional uses of the plant are replaced with other options, use of this crop for a feedstock in biodiesel is an option.

Linseed Oil and Linseed biodiesel

 

Last article for biodiesel feedstocks was Jatropha Oil, Jojoba Oil, & Karania Oil.

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BioDiesel Feedstocks – Jatropha Oil, Jojoba Oil, & Karania Oil 1024 721 Star Oilco

BioDiesel Feedstocks – Jatropha Oil, Jojoba Oil, & Karania Oil

Jatropha Oil, Jojoba Oil, & Karania Oil

We are continuing our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. If you would like to see what feedstocks we have talked about, this is the main page and it links to the ones we have examined.

As a reminder, B20 biodiesel (B20 stands for 20% biodiesel and 80% petroleum diesel) is the drop-in solution for reduced emissions in today’s modern diesel engines. To understand some of the alternate feedstocks that can be used for biodiesel, we are examining a report that Renewable Energy Group (REG) produced in 2009. All certificates of analysis and results are for B100.

This post is a bit different as we have only one successful biodiesel created and two failures. The oils are jatropha oil, jojoba oil and karanja oil.

Jatropha Oil

Jatropha oil comes from the shrub Jatropha curcas, also known as physic nut, Barbados nut, poison nut, bubble bush or purging nut. This plant is a succulent that loses its leaves during the dry season. It is best adapted for arid and semi-arid conditions. The resistance to high degrees of aridity allows it to grow in deserts. This shrub can thrive on only 10 inches of rain for a whole year. It is native to Mexico, Central America, Brazil, Bolivia, Peru, Argentina, and Paraguay. Jatropha curcas is considered a shrub or small tree and can reach a height of 20 ft. or more.Top of a Jatropha plant as part of a hedge

 “Shrubs begin to produce when only 4 – 5 months old, and reach full productivity at about 3 years Under good rainfall conditions, nursery plants bear fruit after the first rainy season, while directly seeded plants bear for the first time after the 2nd rainy season. With vegetative propagation, the first seed yield is higher. At least 2 – 3 tonnes of seeds per hectare can be achieved in semi-arid areas.” (Source)

The seeds contain 27% to 40% oil (Source) and develop in 90 days from the flower to the seed. Trees can have a productive life of 40 to 50 years without tending.

Uses of the plant include medical, edible and as a source of oil for biofuels. The young shoots and even young leaves can be cooked and eaten as a vegetable. The nuts can be eaten but they are purgative and, if eaten in large quantities, can be poisonous.

Medicinal uses include uses the juice from the bark as a treatment for malarial fevers and or using it to treat external burns, scabies and ringworm (Source).

The low maintenance and high oil content makes this plant attractive as a biofuel feedstock. In addition to its use for biodiesel, the oil has been made into jet fuels. In 2008, Air New Zealand flew a plane on 50/50 mix of jatropha oil fuel and jet A1 fuel (Source).

Currently biodiesel is being produced from this plant in the Philippines, Pakistan and Brazil.

 

Jatropha Oil and the biodiesel it produces

Jatropha biodiesel certificate of analysis

Jojoba Oil

Golden jojoba oil was produced from the plant called jojoba (Simmondsia chinensis), an evergreen perennial shrub grown in Arizona, Mexico, and neighboring areas. Some of the common names of this are goat nut, deer nut, pignut, wild hazel, quinine nut, coffeeberry and the gray box bush (Source). The dehulled seeds of jojoba contain 44% of liquid wax ester, which is not a triglyceride.

Seeds on a Female Jojoba BushThis shrub grows to 3 to 6 feet tall and some can get as tall as nearly 10 feet. The fruit is acorn-shaped and .4 inches to .8 inches long.  The seed is dark brown.

Uses of the plant include forage for wild animals such as deer, bighorn sheep and some livestock. In large quantities, the seed meal is toxic to many animals. The oil is different than many of the feedstocks we have discussed.

“Jojoba is unique in that the lipid content of the seeds, which is between 45 and 55 wt.%, is in the form of long-chain esters of fatty acids (FA) and alcohols (wax esters) as opposed to triacylglycerols (TAG) encountered in other vegetable oils and animal fats” (Source).

Because of this, the Jojoba oil wasn’t made into a biodiesel for this study. According to the REG Report:

“The purpose of this project was to transesterify all the feedstocks using the same procedure and if jojoba was done differently, comparisons could not be made with jojoba methyl esters. Jojoba can be transesterified and used as a fuel using a different process.”

Jojoba Oil as a biodiesel feedstock

Karanja Oil

Pure, cold pressed karanja oil was purchased from The Ahimsa Alternative, Inc.Karanja Tree source for Biodiesel Karanja (Pongamia pinnata) is a medium sized evergreen tree, and usually about 25 ft. tall but can grow as large as 80 ft tall (Source). The tree has dark green leaves and the very fragrant flowers of lavender, pink and white.  The tree grows in the humid tropic and can be found in India, China, and Japan. The seed contains 27-39% oil.

Karanja is used for oil production and has some successes in India as a feedstock. In regards to this study, they weren’t able to create a biodiesel fuel using the same procedure as the rest of the feedstocks and therefore there isn’t a sample created to test.

REG’s notes about this oil are as follows:

“Esterification was only able to reduce the FFA (Free Fatty Acid) of the oil to 0.7 wt %. Since 0.5 wt % was the maximum amount of FFA allowed in the feedstock, karanja was not made into biodiesel using the standard procedure. A small scale experiment was performed to see what would happen to the karanja when it was transesterified. A 20 gram sample of karanja oil was used, along with the standard ratios of chemicals as in the other feedstocks for the project. After the water wash step, the karanja formed an emulsion with the water and the phases would not separate. No further refining experiments were done to make karanja suitable for transesterification.”

Karanja Oil

Last article for biodiesel feedstocks was Hemp Oil & High IV and Low IV Hepar

biodiesel-feedstocks-hemp-oil
BioDiesel Feedstocks – Hemp Oil & High IV and Low IV Hepar 1024 683 Star Oilco

BioDiesel Feedstocks – Hemp Oil & High IV and Low IV Hepar

In this post we are going to continue our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report. The feedstocks we are looking into are Hemp Oil & High IV and Low IV Hepar. Here is a link to the main page of feedstocks we have examined so far.

As a reminder B20 Biodiesel (B20 stands for 20% biodiesel and 80% petroleum diesel)  is the drop in solution for reduced emissions in today’s modern diesel engines.   To understand some of the alternate feedstocks that can be used for biodiesel, we are examining a report that Renewable Energy Group (REG) produced in 2009. All certificates of analysis and results are for B100.

Hemp Oil

Hemp seed oil comes from the plant Cannabis sativa and contains significant amounts of linolenic acid. The hemp oil in this study was sourced out of Canada and these seeds have an oil content of 33 percent. Cannabis sativa male picture of flowers

Based on Industrial Hemp Regulations in Canada:

“Industrial hemp includes Cannabis plants and plant parts, of any variety, that contains 0.3% tetrahydrocannabinol (THC) or less in the leaves and flowering heads.

Industrial hemp also includes the derivatives of industrial hemp plants and plant parts. These do not include the flowering parts or the leaves.

Examples of derivatives that are considered industrial hemp include: hemp seed oil (oil derived from seed or grain) and hemp flour.”

THC is the chemical that has psychoactive properties and is what makes the cannabis Marijuana vs Hemp.

This biodiesel sample was created with seed oil that contained less than .03% THC.

Cannabis sativa is an annual flowering plant that originates in Central Asia and is now spread world-wide. The uses of the plant include seed oil, food, recreation, medicine and industrial fiber. (Source)

The centuries of early human cultivation of these plants has created a large variety of strains that look, grow and act different.  Pictured is an example of what a Hemp or Marijuana plant looks like in bloom.

 

Hemp Oil and hemp Biodiesel

Hemp Oil Biodiesel Certificate of Analysis

 

 

Hepar, High Iodine Value and Low Iodine Value (IV)

In this situation, Hepar is a byproduct of the heparin manufacturing process. Pharmaceutical grade heparin is derived from the mucosal tissues and of animals, such as pig intestines or cow lungs. (Mucosal tissues are part of the immune system it is the barrier between potential pathogens and the body.) Heparin is a medicine that is used as an anticoagulant.  Since the creation of Heparin is a industry secret, it is difficult to find much information about the byproduct Hepar.

High IV Hepar and Biodiesel

High IV Hepar Biodiesel Certificate of Analysis Low IV Hepar BioDiesel Certificate of Analysis

 

Last article for biodiesel feedstocks was Evening Primrose Oil & Fish Oil

about-diesel-fuel
About Diesel Fuel 1024 512 Star Oilco

About Diesel Fuel

Bulk Diesel Fuel Frequently Asked Questions

Ultra Low Sulfur Diesel is 15 PPMDyed Off-Road Diesel

Where your diesel comes from and what you need to know about ASTM Diesel Standards and ISO cleanliness code.

Where do Pacific Northwest vendors get their fuel?

In the Pacific Northwest, diesel is fungible. Everyone buys their fuel from each other in some way or another.  

This means that every refiner is typically expecting to mix their diesel and gasoline products. The real difference is in the care a vendor takes to filter the fuel, additize and continuously check their fuel quality. If you are buying at the absolute lowest price possible, know that there is an incentive to skip any added value of quality assurance.

Through its Pacific Operations unit, Kinder Morgan operates approximately 3,000 miles of refined products pipeline that serves Arizona, California, Nevada, New Mexico, Oregon, Washington and Texas. With roots dating back to 1956, it is the largest products pipeline in the Western U.S., transporting more than one million barrels per day of gasoline, jet fuel and diesel fuel to our customers. The company-owned terminals also provide additional services, such as liquid petroleum product storage and loading facilities for delivery trucks.

Diesel Fuels

In the United States, diesel fuel is controlled according the American Society for Testing and Materials Standard D975-97.  This standard describes a limited number of properties that diesel fuels must meet.  It should be noted that the requirements are all performance- based.  They do not mandate the composition of the fuel, only the specific performance related requirements demanded of a fuel for a diesel engine.  The requirements of D975 are described below. 

ASTM Specifications for Diesel Fuel Oils (D975)*

* You can go to the source of ASTM HERE if you have an interest in really getting in depth.

Diesel fuel is characterized in the United States by the ASTM standard D975.  This standard identifies five grades of diesel fuel. We are only going to talk about the two most popular commercially diesel fuel used — No 1 and No. 2 diesel. The ASTM D975 standard is made up of a series of different tests that check the characteristic ranges of a fuel to confirm it is adequate to operate in your equipment. In simple terms, they are checking for specific gravity, the vapor point (when it turns into a gas), the flash point (when it catches fire), the dirt content, water content (how much microscopic entrained water), and a host of other requirements diesel must meet in order to be legal to be sold for use in your engine.

Grade No. 1-D and Ultra-Low Sulfur 1-D: This is a light distillate fuel for applications requiring a higher volatility fuel to accommodate rapidly fluctuating loads and speeds, as in light trucks and buses. The specification for this grade of diesel fuel overlaps with kerosene and jet fuel, and all three are commonly produced from the same base stock. One major use for No. 1-D diesel fuel is to blend with No. 2-D during winter to provide improved cold flow properties.  Ultra Ultra-Low sulfur fuel is required for on-highway use with sulfur level < 0.05%. 

Grade No. 2-D and Ultra-Low Sulfur 2-D:  This is a middle- or mid-grade distillate fuel for applications that do not require a high volatility fuel. Typical applications include high-speed engines that operate for sustained periods at high load. Ultra-Low sulfur fuel is required for on-highway use with sulfur level < 0.05%.

RecologyDealing with Dirty Fuel and Today’s Tier 4 Engines

Water and dirt are the biggest concerns for fuel quality. Why? Because no matter how perfect fuel is refined, these two elements can find their way into fuel and crash its performance. Water and dirt often build up in tanks just from the temperature change between night and day, causing a bulk fuel tank to breathe. Condensation and dust can also find their way into a bulk storage tank. If not addressed, they build up and will cause mechanical failures.

Dirty fuel will cause premature parts failure in equipment of any age. But newer equipment has far tighter tolerances than what we saw in previous decades. Today’s new and improved Tier 4 rail injector engines are more efficient, they burn cleaner, and run better, they are more powerful than ever before. But there are things that make fuel quality more important than ever. Because of the extremely high pressures (upwards of 35,000psi at the injector tip), the possibility of damage from dirty wet fuel is more prevalent than ever. This damage is much more pronounced in newer equipment with High Pressure Common Rail (HPCR) fuel systems. Hard particulate is commonly referred to as “dirt,” but is in fact made up of a wide variety of materials found at job sites (coal, iron, salt, etc.), generated by fuel tanks and lines (rust, corrosion, etc.) and inside engines (carbonaceous materials and wear particles).

Frequent diesel fuel filter changes — as well as the expensive, and time consuming, task of cleaning diesel fuel tanks — have become acceptable periodic maintenance, instead of a warning signal, for diesel engine failure. Diesel fuel filter elements should last a thousand hours or more, and injectors should endure 15,000 hours. However, since diesel fuel is inherently unstable, solids begin to form and the accumulating tank sludge will eventually clog your diesel fuel filters, ruin your injectors and cause diesel engines to smoke.

Symptoms

  • Clogged and slimy filters
  • Dark, hazy fuel
  • Floating debris in tanks
  • Sludge build up in tanks
  • Loss of power and RPM
  • Excessive smoke
  • Corroded, pitted injectors
  • Foul odor

The solids that form as the result of the inherent instability of the diesel fuel and the debris formed in the natural process of fuel degradation will accumulate in the bottom of your fuel tank. The sludge will form a coating or “bio-film” on the walls and baffles of the fuel tank, plug your fuel filters, adversely impact combustion efficiency, produce dark smoke from the exhaust, form acids that degrade injectors and fuel pumps, and impact performance. Eventually, fouled diesel fuel will clog fuel lines and ruin your equipment.

The Bigger Picture: ISO (International Standardization Organization)ISO Chart 1

In today’s world, the definition of what constitutes clean or dirty fuel is critically important and, as such, fuel cleanliness levels are now measured and reported according to the ISO Cleanliness Code 4406:1999. The International Organization for Standardization (ISO) created the cleanliness code to quantify particulate contamination levels per milliliter of fluid at three sizes: 4μ, 6μ, 14μ. Microns.

Fuel Cleanliness vs. Engine Technology

Fuel cleanliness levels using the ISO4406:1999 method were officially documented as a global standard only as recently as 1998 with the development of the Worldwide Fuels Charter (WWFC). Since its inception, the charter has established a minimum cleanliness level for each of the diesel fuels under various available categories around the world.

Most mainstream engine OEM’s now subscribe to these standards. Interestingly (and somewhat troubling to note), however, is that fuel cleanliness levels as specified by engine OEM’s and the WWFC have not changed since their inception in 1998, despite the enormous advances in fuel injection technology. This relationship is best represented in the previous table that identifies the advances in fuel injection systems and clearly highlights how OEM’s and the WWFC have not responded to reduce fuel cleanliness in accordance with advancements in technology.

Diesel Fuel Injection – Advancing Technologies & Cleanliness Levels

ISO Chart 4This table  identifies that, over time, fuel injector critical clearances have halved and fuel pressures have doubled, yet the level of fuel cleanliness being specified has not changed in accordance with such advancements. In fact, the same cleanliness levels specified in 2000 are still being used today despite these magnificent technological design advancements by engine manufacturers worldwide.

Leading fuel injector manufacturers around the world have clearly identified and communicated that they require ULSD fuels with ISO fuel cleanliness levels as low as ISO12/9/6 to maintain ultimate performance and reliability. It is here where we see an enormous mismatch in what the fuel injection OEM desires as a fuel cleanliness level, to what the engine OEM’s and the WWFC are advising the industry. The following table identifies the discrepancies in fuel cleanliness levels.

Diesel Cleanliness Levels

 ISO Chart 3                        

 

 

 

 

 

WWFC Diesel Category Fuel Cleanliness Standards                                                                                                      ISO Chart 5

 

 

 

 

Damage Caused by Hard Particulate

Hard particulates cause problems with moving parts in the fuel system. This can lead to starting problems, poor engine performance, idling issues and, potentially, complete engine failure. All too common, hard particulates damage engines.

The spray pattern generated by the HPCR injector is critical for proper combustion and overall fuel system performance. (1) sm-injector-with-red-light-Bosch

It must be extremely precise in terms of quantity, distribution and timing. Ball seat valves are sealed with balls that are only 1mm in diameter. A good seal is absolutely necessary for proper injection. Damage from erosive wear, such as shown below, will cause over fueling, leading to decreased fuel efficiency and eventually shut you down altogether.

hpcr injector damaged by hard particulate(3) high-pressure-fuel-system-wear

Pump performance can also be compromised by scoring and abrasive wear. These issues are magnified by tighter tolerances and extreme pressures in HPCR engines. In these circumstances, it is the smallest particles (1-5 microns in size) that cause the most damage, virtually sand blasting part surfaces.

Allowable Levels of Hard Particulate 

(4) dirt-in-vs-allowed-in-1000-gal-dieselIn some parts of the world, 10,000 gallons (38,000 liters) of “typical” diesel contains 1-1/2 lbs (700 grams) of hard particulate; this is 1000 times more than the 1/4 oz. (0.7 grams) per 10,000 gallons (38,000 liters) that is allowed by the cleanliness requirements of high pressure common rail fuel systems. In reality, there is no “OK” level of hard particulate. Injector manufacturers are very clear that damage caused by hard particulate reaching the engine is not a factory defect, but rather the result of dirty diesel that is not fit for use in HPCR fuel systems. At the end of the day, the end user is responsible for the fuel he puts into his equipment, and the consequences thereof.

How Dirt Enters Fuel

Dust and dirt are all around us, especially on job sites. Diesel fuel is fairly clean when it leaves the refinery but becomes contaminated each time it is transferred or stored. Below you will find some of the key contributors of fuel contamination:

Pipelines: Most pipelines are not new, and certainly not in pristine condition. Corrosion inhibitors are added at most refineries to help protect pipelines, but rust and other hard particulate is nevertheless picked up by the fuel that flows through them.

Barges and rail cars: How often are they drained and scrubbed out? What was in the last load? Where did it come from? How much of it was still in the tank when your load was picked up? How long was it in transit? Is the tank hermetically sealed? There are many opportunities for contaminants to make their way into the fuel.

Terminal tanks: Terminal tanks usually see a high rate of turnover, so there is not much time for the fuel to pick-up contamination from outside ingress. Has the tank ever received a “bad load” from a pipeline or a barge? Has larger dirt had a chance to settle on the bottom of the tank? How often has it been cleaned out? Was it just filled? Did the bottom get churned up in the process? How full was the tank when your fuel was loaded into the delivery truck? There are many variables that can affect fuel cleanliness.

Delivery trucks: All the same issues that apply to stationary tanks also apply to tanker trucks, except that truck tanks never get a chance to settle. In addition, have you ever considered how much dirt gets into that tanker while it is delivering fuel to a customer, potentially a customer in an extremely dusty environment? As fuel flows out, air is sucked in to displace it. Is there anything protecting the inside of the tank from all the dust in the air? Generally not. Venting is typically completely unprotected, as seen in the image to the right.

Storage tanks: Onsite bulk storage tanks typically see less rapid turn-over than terminal tanks. In addition to those issues, yard and jobsite tanks can also develop serious problems with other sources of contamination, such as the ingress of dirt and water, condensation, rust, corrosion, microbial growth, glycerin fall-out and additive instability. Time and temperature become big factors affecting fuel quality.

Dispensing process: How far does your diesel need to travel between the bulk tank and the dispenser? The more pipe it runs though, the more potential there is for contamination. Are your dispenser nozzles kept clean? Are they ever dropped on the ground? Then what? What about the vehicles’ fuel tank inlets, are they clean? Think about the extremely tight tolerances in your fuel system, then take another look at housekeeping issues. You will see them through new eyes.

Onboard fuel tanks: Contamination continues even after the fuel is in the equipment. What has that tank seen in the past? Has it been left stagnant for long periods? What kind of protection is there on the equipment’s air intake vents? Heavy equipment does hard, dirty work.

Engines: Unfortunately, even if the fuel in your tank could be perfect, additional contamination is generated by the fuel system itself. Wear particles are created by mechanical friction. High heat and extreme pressure generated inside the modern engine, lead to coking and the creation of carbon products at the injector. Much of this internally-produced particulate is returned to the fuel tank, along with the unburned diesel.

The Bottom Line

No one gets special fuel, no one has better fuel, no one has cleaner fuel. Diesel fuel vendors get the same fuel, from the same pipeline, delivered to the same terminals. We all wait in the same lines with our tank trucks to get that same fuel. So ask yourself: Given that the fuel is the same, what sets one vendor apart from all the others? Star Oilco Premium Diesel fuel is treated with Hydrotex PowerKleen® additive running through Donaldson filtration systems.

Clean, dry, premium diesel

FURTHER READING ON DIESEL FUEL:

Read about Star Oilco’s approach to Fuel Quality Assurance: Star Oilco – Precision Fuel Management

Read about dealing with biological growth in your diesel tank: Bioguard Plus 6 biocide treatment for diesel

Get Chevron’s Technical Manual to Diesel Fuel (essentially an easy to read text book on diesel): Chevron’s Fuel Technical Review

Get a white paper from Donaldson Filtration on tier 4 engines and fuel cleanliness: Donaldson on Tier 4 Engine Fuel Contamination

Read more about Donaldson Desiccant Breathers for bulk diesel tanks: Why use a Donaldson Desiccant Breather for a bulk diesel storage tank.

biodiesel-feedstocks-evening-primrose-and-fish-oil
BioDiesel Feedstocks – Evening Primrose & Fish Oil 1024 516 Star Oilco

BioDiesel Feedstocks – Evening Primrose & Fish Oil

The two feedstocks we are looking into this time are Evening-Primrose Oil and Fish Oil. Here is a link to the main page of feedstocks we have examined so far.  As we continue our deeper look into different types of feedstock that Renewable Energy Group (REG) studied in 2009 in the Feedstock and Biodiesel Characteristics Report.

Evening-Primrose Oil

The Common Evening-primrose (Oenothera biennis) is also known as evening star, sun drop, German rampion, weedy evening primrose, hog weed, King’s cure-all, or fever-plant.  This plant is native to North America and grows throughout most of the continental US and in Canada. Oenothera biennis (common evening primrose). Flowers and buds

A unique aspect of this plant is that it has a bright yellow flower blooms that is open in the evening and then is closed at noon.(source)  This plant can grow up to 6 feet tall and is a biennial, meaning it lives for 2 years flowering the second year. The plant has leafy branched stems that are ridged and usually has fine white hair.

According to Friends of the wild flower:

“The leaves are both basal and stem. Basal leaves taper to short stalks and form a rosette in the first year of growth. The stem leaves develop the second year when the flowering stem rises; they are alternate, lance-like, wavy edged, slightly toothed, slightly hairy on both surfaces, with one main central vein and fine laterals. They can be up to 8 inches long near the base and 1/4 as wide, but become considerable shorter near the top of the stem.”

A simple google search shows that this plant has medicinal uses, known by some of the indigenous tribes of North America for hundreds of years. Some of the common uses were to treat bruises with a poultice and use the leaves in a tea as a stimulant. The drug in the plant can be used as a sedative and and as an astringent. The oil the plant produces is full of fatty acids and is sold as a dietary supplement.

The roots of the plant can also be boiled and eaten if they haven’t flowered yet. The leaves of the plant can be used before flowering in salads. Even the flowers can be eaten and are said to have a sweet taste.

The ability of the plant to grow in arid conditions and not need a lot of water adds potential of this plant to provide nutrients, oil and medicinal material for drier locations.

 

Evening Primrose Oil and the Bio-Diesel it produces

Evening Primrose Certificate of Analysis

 

 

Fish Oil

The Fish Oil that REG used simply says “Fish oil was obtained from a commercially available source in Peru.”  The types of fish that are used to make fish oil in Peru are anchovy, herring, menhaden or sardines.

This source was likely the same that would be purchased to produce fish oil nutritional supplements or other food products. In the production of biodiesel there is a large potential for this product. Many of the toxins and imperfections that need to come out for human consumption wouldn’t effect the creation of biodiesel.  Fish oil that is produced in the process of fish processing has potential of removing waste from going to landfills. Several scholarly papers have been written on it.  If you would like to know a little more this article was written on the waste from salmon processing in Canada.

Fish Oil and the Fish Bio-Diesel that it produces

Fish Oil Bio-diesel Certificate of Analysis

 

Last article for biodiesel feedstocks was Coconut Oil and Coffee Oil.